- PII
- S3034618525090029-1
- DOI
- 10.7868/S3034618525090029
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 61 / Issue number 9
- Pages
- 443-449
- Abstract
- It was discovered earlier that the calix[]arene sulfonic acids have a record high proton conductivity, so that it was suggested that lithium salts of calix[]arene sulfonic acids plasticized with aprotic solvents should also have ionic conductivity. It was found that the medium salt of calix[]arene sulfonic acid in combination with propylene carbonate as a plasticizer has an ionic conductivity of 10–10 mS/cm, which makes it a promising material for further study and use as an electrolyte for lithium-ion batteries.
- Keywords
- металл-ионные аккумуляторы твердотельные электролиты каликс[]арен ионная проводимость пропиленкарбонат
- Date of publication
- 25.02.2026
- Year of publication
- 2026
- Number of purchasers
- 0
- Views
- 38
References
- 1. Balogun, M.S., Yang, H., Luo, Y., Qiu, W., Huang, Y., Liu, Z.Q., and Tong, Y., Achieving High Gravimetric Energy Density for Flexible Lithium Ion Batteries Facilitated by Core-Double-Shell Electrodes, Energy Environ. Sci., 2018, vol. 11, p. 1859. DOI: 10.1039/C8EE00522B
- 2. Yoshino, A., The Birth of the Lithium-Ion Battery, Angew. Chem. Int. Ed., 2012, vol. 51, p. 5798. DOI: 10.1002/anie.201105006
- 3. Croce, F., Appetecchi, G.B., Persi, L., and Scrosati, B., Nanocomposite polymer electrolytes for lithium batteries, Nature, 1998, vol. 394, p. 456. DOI: 10.1038/28818
- 4. Zhou, L., Zhang, K., Hu, Z., Tao, Z., Mai, L., Kang, Y.M., Chou, S.L., and Chen, J., Recent Developments on and Prospects for Electrode Materials with Hierarchical Structures for Lithium-Ion Batteries, Adv. Energy Mater., 2017, vol. 8, 1701415. DOI: 10.1002/aenm.201701415
- 5. Chen, C., Xie, X., Anasori, B., Sarycheva, A., Makaryan, T., Zhao, M., Urbankowski, P., Miao, L., Jiang, J., and Gogotsi, Y., MoS2-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries, Angew. Chem. Int. Ed., 2018, vol. 57, p. 1846. DOI: 10.1002/anie.201710616
- 6. Jiang, Y., Zhang, Y., Yan, X., Tian, M., Xiao, W., and Tang, H., A sustainable route from fly ash to silicon nanorods for high performance lithium ion batteries, Chem. Eng. J., 2017, vol. 330, p. 1052. DOI: 10.1016/j.cej.2017.08.061
- 7. Xu, K., Electrolytes and Interphases in Li-Ion Batteries and Beyond, Chem. Rev., 2014, vol. 114, p. 11503. DOI: 10.1021/cr500003w
- 8. Aravindan, V., Gnanaraj, J., Madhavi, S., and Liu, H.-K., Lithium-Ion Conducting Electrolyte Salts for Lithium Batteries, Chem. Eur. J., 2011, vol. 17, p. 14326. DOI: 10.1002/chem.201101486
- 9. Lex-Balducci, A., Henderson, W.A., and Passerini, S., Electrolytes for lithium ion battery materials in Lithium ion batteries: advanced materials and technologies, Yuan, Y., Liu, H., and Zhang, J., Eds, Boca Raton, FL: CRC Press, 2011, p. 121.
- 10. Henderson, W.A., Nonaqueous Electrolytes: Advances in Lithium Salts in Electrolytes for Lithium and Lithium-Ion Batteries, Jow, T.R., Xu, K., Borodin, O., and Ue, M., Eds, New York, NY: Springer, 2014, vol. 58, p. 476. DOI: 10.1007/978-1-4939-0302-31
- 11. Бушкова, О.В., Ярославцева, T.В., Добровольский, Ю.А. Новые соли лития в электролитах для литий-ионных аккумуляторов (обзор). Электрохимия. 2017. Т. 53. С. 763. DOI: 10.7868/S0424857017070015 @@ Bushkova, O.V., Yaroslavtseva, T.V., and Dobrovol-sky, Yu.A., New lithium salts in electrolytes for lith-ium-ion batteries (Review), Russ. J. Electrochem., 2017, vol. 53, p. 677. DOI: 10.1134/S1023193517070035
- 12. Younesi, R., Veith, G.M., Johansson, P., Edstrombe, K., and Veggea, T., Lithium salts for advanced lithium batteries: Li-metal, Li-O2, and Li-S, Energy Environ. Sci., 2015, vol. 8, p. 1905. DOI: 10.1039/C5EE01215E
- 13. Писарева, А.В., Писарев, Р.В., Карелин, А.И., Шмыглева, Л.В., Антипин, И.С., Коновалов, А.И., Соловьева, С.Е., Добровольский, Ю.А., Алдошин, С.М. Протонная про-водимость каликс[n]арен-пара-сульфокислот (n = 4, 8). Изв. АН, Сер. хим. 2012. Т. 10. С. 1877. @@Pisareva, A.V., Pisarev, R.V., Karelin, A.I., Shmy-gleva, L.V., Antipin, I.S., Konovalov, A.I., Solovie-va, S.E., Dobrovolsky, Yu.A., and Aldoshin, S.M., Proton conductivity of calix[n]arene-para-sulfon-ic acids (n = 4, 8), Russ. Chem. Bull., 2013, vol. 61, p. 1892. DOI: 10.1007/s11172-012-0263-7
- 14. Scharff, J.P., Mahjoubi, M., and Perrin, R., Synthesis and asid-base properties of calix[4], calix[6] and calix[8]arene p-sulfonic acids, New. J. Chem., 1991, vol. 15, p. 883.
