RAS Chemistry & Material ScienceЭлектрохимия Russian Journal of Electrochemistry

  • ISSN (Print) 0424-8570
  • ISSN (Online) 3034-6185

DEVELOPMENT OF MAGNETRON PROTECTIVE COATINGS OF CHROMIUM NITRIDES AND CARBIDES ON TITANIUM BIPOLAR PLATES OF A FUEL CELL WITH A PROTON-EXCHANGE MEMBRANE

PII
S3034618525080028-1
DOI
10.7868/S3034618525080028
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 61 / Issue number 8
Pages
367-379
Abstract
The article presents the results of a study of titanium bipolar plates of fuel cells with a proton-exchange membrane with functional coatings based on chromium nitride, carbide and carbonitride obtained by magnetron sputtering of a chromium target in argon plasma with different nitrogen and propane contents. The microstructure and morphology of pure CrN and CrC films on titanium and composite coatings of chromium carbonitride CrNС were studied. It was shown that protective chromium carbide films obtained by adding propane to argon plasma exhibit increased contact surface resistance at the gas diffusion electrode-bipolar plate interface (CrC: = 119.4 mOhm·cm). However, for chromium carbonitride coatings this indicator is only 1.9 mOhm·cm, which is lower than for pure CrC films and significantly lower than for uncoated titanium (Ti: = 38.9 mOhm·cm). This is an important indicator for using such bipolar plates in fuel cell power plants with high specific characteristics. Corrosion measurements performed using conventional techniques showed that the corrosion current for chromium carbonitride was less than 1 µA/cm, which is better than uncoated titanium and pure CrN and CrC films.
Keywords
топливный элемент с протонообменной мембраной биполярная пластина титан защитные покрытия ток коррозии поверхностное контактное сопротивление
Date of publication
25.02.2026
Year of publication
2026
Number of purchasers
0
Views
13

References

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