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RAS Chemistry & Material ScienceЭлектрохимия Russian Journal of Electrochemistry

  • ISSN (Print) 0424-8570
  • ISSN (Online) 3034-6185

Comparison of electrochemical characteristics of thin-film batteries with a composite anode Si@O@Al and lithium metal formed by in situ method

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PII
10.31857/S0424857024090056-1
DOI
10.31857/S0424857024090056
Publication type
Article
Status
Published
Authors
A. S. Rudy
  • Affiliation: P.G. Demidov Yaroslavl State University
S. V. Kurbatov
  • Affiliation: P.G. Demidov Yaroslavl State University
Volume/ Edition
Volume 60 / Issue number 9
Pages
636-647
Abstract
This study compares the electrochemical characteristics of solid-state thin-film lithium-ion batteries with two different structures: Ti/Anode/LiPON/LiCoO2/Ti (with an anode) and Ti/LiPON/LiCoO2/Ti (anode-free). Si@O@Al composite anode with thicknesses of 154 and 15 nm, as well as pre-lithiated LixSi@O@Al composite with a thickness of 192 nm, were used as anodes. In anode-free batteries, the lithium anode was formed by the in situ method. Batteries with 154 nm Si@O@Al and LixSi@O@Al anodes have good cyclability due to their moderate volume change during lithium-ion insertion/extraction and reliable adhesion to the LiPON solid electrolyte. These batteries are promising in terms of high energy density due to the lithium anode formation in situ, although they have poor cycling performance due to peeling off the upper current collector. The introducing of a Si@O@Al thin film with a thickness of ~15 nm between the LiPON and the current collector allows maintaining the high energy density that is inherent in batteries with lithium anodes, while also improving their cyclability.
Keywords
тонкопленочный литий-ионный аккумулятор удельная емкость удельная энергия циклируемость
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
2

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