RAS Chemistry & Material ScienceЭлектрохимия Russian Journal of Electrochemistry

  • ISSN (Print) 0424-8570
  • ISSN (Online) 3034-6185

ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE TO FORMATE IN ACID ELECTROLYTE IN ACETYLENE BLACK GAS DIFFUSION ELECTRODE WITH A LEAD CATALYST

PII
10.31857/S0424857023100092-1
DOI
10.31857/S0424857023100092
Publication type
Status
Published
Authors
Volume/ Edition
Volume 59 / Issue number 10
Pages
606-609
Abstract
The possibility of electrosynthesis of formate from CO2 at a current density of 50–190 mA/cm2 in sulfuric acid aqueous solutions (pH 2–2.5) in a gas diffusion electrode with a lead electrocatalyst deposited on acetylene black was studied. It is shown that with an appropriate selection of the electrolyte composition, it is possible to carry out the electrosynthesis process with parameters that practically differ little from those in alkaline solutions. The highest current efficiency of 74% was obtained at a potential of -1.89 V, a current density of 150 mA/cm2 in an electrolyte of 0.5 M K2SO4 + 0.083 M H2SO4.
Keywords
диоксид углерода муравьиная кислота формиат электрокаталитическое восстановление газодиффузионный электрод
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
6

References

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