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RAS Chemistry & Material ScienceЭлектрохимия Russian Journal of Electrochemistry

  • ISSN (Print) 0424-8570
  • ISSN (Online) 3034-6185

ELECTROCHEMICAL BEHAVIOR OF COMPLEXES OF COBALT AND ZINC METHOXYPHENOXYPHTHALOCYANINES

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PII
S3034618525060024-1
DOI
10.7868/S3034618525060024
Publication type
Article
Status
Published
Authors
A.E. Rassolova
  • Affiliation: Ivanovo State University of Chemical Technology, Research Institute of Macroheterocyclic Compounds
N.M. Berezina
  • Affiliation: Ivanovo State University of Chemical Technology, Research Institute of Macroheterocyclic Compounds
M.I. Bazanov
  • Affiliation: Ivanovo State University of Chemical Technology, Research Institute of Macroheterocyclic Compounds
V.E. Maizlish
  • Affiliation: Ivanovo State University of Chemical Technology, Research Institute of Macroheterocyclic Compounds
M.V. Tesakova
  • Affiliation: G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
V.I. Parfenyuk
  • Affiliation: G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 61 / Issue number 6
Pages
287-298
Abstract
The electrochemical behavior of a number of isomers of methoxyphenoxy derivatives of cobalt phthalocyanine {CoPc[4-(x-OCHOPh)] and CoPc[3-(x-OCHOPh)], where x = 4/, 3/, or 2} in an aqueous alkaline solution and ZnPc[4-(x-OCHOPh)], where x = 4/, 3/, or 2/ in a CHCl medium was studied for the first time using cyclic voltammetry. A comparative analysis of the electrochemical behavior and changes in the electrocatalytic activity of cobalt phthalocyanines in the reaction of molecular oxygen electroreduction depending on the functional substitution in the macrocycle molecule is given. It is shown that for the compounds (CoPc[4-(x-OCHOPh)] and CoPc[3-(x-OCHOPh)]) the processes of oxidation (Co ⇔ Co) and reduction of the central metal ion (Co ⇔ Co) are recorded, as well as two successive one-electron stages of electroreduction of the phthalocyanine ligand. It is established that the studied cobaltphthalocyanine derivatives are quite effective systems for the process of electroreduction of molecular oxygen. For ZnPc[4-(x-OCHOPh)], where x = 4/, 3/or 2/, the formation of polyphthalocyanine films was detected in the process of electrooxidation of monomers in dichloromethane.
Keywords
фталоцианины комплексы щелочной электролит электрокатализ молекулярный кислород
Date of publication
11.01.2026
Year of publication
2026
Number of purchasers
0
Views
45

References

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