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RAS Chemistry & Material ScienceЭлектрохимия Russian Journal of Electrochemistry

  • ISSN (Print) 0424-8570
  • ISSN (Online) 3034-6185

Electrodeposition of Photosensitive Layers Based on Conducting Polymers and Zinc Phthalocyaninate, Their Structure and Photoelectrical Properties

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PII
10.31857/S0424857024060053-1
DOI
10.31857/S0424857024060053
Publication type
Article
Status
Published
Authors
O. L. Gribkova
  • Affiliation: A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A. A. Nekrasov
  • Affiliation: A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 60 / Issue number 6
Pages
430-441
Abstract
Photosensitive hybrid layers were obtained by electrochemical polymerization of pyrrole and 3,4-ethylenedioxythiophene (EDOT) in the presence of water-soluble sodium salt of zinc octa(3ʹ,5ʹ-dicarboxyphenoxy)phthalocyaninate (ZnPc) containing 16 ionogenic carboxylate groups. It was found that the process of electrodeposition of hybrid layers most effectively occurs in galvanostatic and potentiostatic modes on the sublayer of the PEDOT-polyacid complex. The electronic and chemical structure and morphology of hybrid layers of polypyrrole (PPy) obtained in the presence of ZnPc were studied. Possible reasons are considered that the measured values of photosensitivity and external quantum yield of charge carrier generation in PPy-ZnPc are several times higher than in PEDOT-ZnPc.
Keywords
проводящие полимеры полипиррол PEDOT водорастворимый фталоцианин электрохимическая полимеризация фоточувствительность фотогенерация
Date of publication
27.06.2024
Year of publication
2024
Number of purchasers
0
Views
29

References

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